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Looking at slotting Acid Arrow with the procs from Posi's Blast and/or Shield Breaker. Do they work and if anyone has gone this route, is it advisable?
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Yes, yes and yes if you have the slots to spare. Pack it with procs. Posi's Blast, Shield Breaker, Lady Grey's and Achilles' Heel.
Ahh good to know, thanks! 
Endure. In enduring grow strong
Whirl | Blankets | Scarlet Infusion | Pinkfire Dreamery | Purple Vanda | Zichar | Auxin Arcua | Ebonmist | Gelid Storm | Serrated Edge | Natural Conviction | Immiscible | Nucleation Effect | Strawberry Slush | Ur Ir Aer | Christabella Cook | Severe Tinnitus
If you have the slots to spare I would slot some procs too. However, I have always looked at them like a bonus and not something to be relied on to hit everytime.
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Looking at slotting Acid Arrow with the procs from Posi's Blast and/or Shield Breaker. Do they work and if anyone has gone this route, is it advisable?
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Yes, yes and yes if you have the slots to spare. Pack it with procs. Posi's Blast, Shield Breaker, Lady Grey's and Achilles' Heel.
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I seriously considered the procs, but for me, the bonuses from the full Lady Grey set seem to be more helpful overall than the potential for additional damage, etc. (Obviously, the Lady Grey proc is there either way.)
Now, on my Stormers, I use the 3 damage procs in Freezing Rain since they have two shots at firing per application. I was under the impression that they only have the one shot to fire with Acid Arrow, when initially applied. Is that correct?
"How do you know you are on the side of good?" a Paragon citizen asked him. "How can we even know what is 'good'?"
"The Most High has spoken, even with His own blood," Melancton replied. "Surely we know."
I believe you are correct Melancton. The proc will only fire on the initial hit.
Looking at slotting Acid Arrow with the procs from Posi's Blast and/or Shield Breaker. Do they work and if anyone has gone this route, is it advisable?
Thinking aloud, the smallish radius may not be very conducive but I find Seeds, wait a moment then + Roots can get me good clumps.
Endure. In enduring grow strong
Whirl | Blankets | Scarlet Infusion | Pinkfire Dreamery | Purple Vanda | Zichar | Auxin Arcua | Ebonmist | Gelid Storm | Serrated Edge | Natural Conviction | Immiscible | Nucleation Effect | Strawberry Slush | Ur Ir Aer | Christabella Cook | Severe Tinnitus