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For one reason or another, I have been unable to take a print screen of my character in the character selection portion. In game I can take as many as I want, but the CS doesn't allow me to do it
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Once you hit print screen in the CS menu. Open MS Paint (or any graphic/paint program) and select Edit->Paste. The CS menu only copies the screen to your clipboard, you need to paste it into a document/image to see it. You can even Paste it into Word.